C[sub 60] fullerene as carbon source for diamond synthesis

Journal Article · Thu Dec 09 04:00:00 EST 1993 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100151a047· OSTI ID:7302212

Bocquillon, G; Bogicevic, C ^[1]; Fabre, C; Rassat, A ^[2]

---

1. CNRS, Meudon (France)
2. ENS, Paris (France)

The C[sub 60] fullerene was used as the carbon source to carry out the catalyzed synthesis of diamond, at 6.7 GPa and temperatures between 1200 and 1850[degrees]C; the catalysts used were Ni, Co, and a Co alloy. Under these conditions, the graphite used as the carbon source gave a diamond yield of about 90%; the yield with C[sub 60] depended on the catalyst. With Co, about the same quantity of diamond was obtained from C[sub 60] as from graphite, whereas almost no diamond was synthesized when pure C[sub 60] was used as the carbon source with Ni and the Co alloy as catalysts. The diamond yield recovered to a high level with these two catalysts when a small quantity (about 10%) of graphite was added to the C[sub 60] fullerene. This effect of the addition of graphite to a non-graphite carbon in the synthesis of diamond is different from that observed with amorphous carbons. In all these experiments under high pressure and high temperature with Ni, Co, or Co alloy, the C[sub 60] fullerene was destroyed and transformed into diamond, graphite, or poorly crystallized carbon. 27 refs., 2 figs., 1 tab.

• OSTI ID: 7302212
• Journal Information: Journal of Physical Chemistry; (United States), Journal Name: Journal of Physical Chemistry; (United States) Vol. 97:49; ISSN JPCHAX; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360601 -- Other Materials-- Preparation & Manufacture
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
ALLOYS
CARBON
CATALYSIS
COBALT
COBALT ALLOYS
COHERENT SCATTERING
DATA
DIAMONDS
DIFFRACTION
ELEMENTAL MINERALS
ELEMENTS
EXPERIMENTAL DATA
FULLERENES
GRAPHITE
INFORMATION
METALS
MINERALS
NICKEL
NONMETALS
NUMERICAL DATA
SCATTERING
SYNTHESIS
TRANSITION ELEMENTS
X-RAY DIFFRACTION