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U.S. Department of Energy
Office of Scientific and Technical Information

Waterflood process taking advantage of chromatographic dispersion

Patent ·
OSTI ID:7301164

Surfactant adsorption can be reduced by using a high molecular weight component and a low molecular weight component in aqueous saline solutions. The process involves injecting (1) an aqueous saline surfactant solution containing a surfactant having a high molecular weight component and a low molecular weight component, (2) a slug of aqueous less-saline solution containing a minor amount of the low molecular weight component of the surfactant, and (3) saline flooding water. In this process, the high molecular weight component which is preferentially adsorbed in the first step, is desorbed by the slug of less-saline solution in the second step and forms a second surfactant bank. Laboratory tests on sandpacks used the higher molecular weight surfactant Alconate 80, the lower molecular weight component Pyronate 50, sodium carbonate and sodium tripolyphosphate for further reduction of surface tension, and Kelzan biopolymer for viscosity control. These studies recovered up to 100 percent of the oil left after waterflooding.

Assignee:
Mobil Oil Corp.
Patent Number(s):
US 3437140
OSTI ID:
7301164
Country of Publication:
United States
Language:
English