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Displacement mechanisms of micellar solutions

Journal Article · · J. Pet. Technol.; (United States)
DOI:https://doi.org/10.2118/1847-2-PA· OSTI ID:7299564
Microscopic phenomena were observed photographically in a specially constructed glass flow model and macroscopic data were taken from constant rate, tertiary displacements conducted in Berea sandstone cores. A micellar solution slug completely removes oil from the portion of rock it contacts, but incompletely displaces the interstitial water. For a given composition of micellar solution, the amount of water dispersed increases with decreasing water salinity. Thickened water is capable of displacing slug and residual water. A water-external emulsion, that can be infinitely diluted with water, is spontaneously formed by the micellar slug and low salt water (e.g. thickened water). Naphtha, water, sodium hydroxide, petroleum sulfonate, isopropanol and nonyl phenol were combined to form the micellar solution. The thickened water contained Dow Pusher. A consolidated Berea sandstone core was saturated with a sweet, black, 7-cp, 36.4/sup 0/ API gravity Illinois crude, then waterflooded to residual oil. A 5 percent PV micellar slug recovered all of the oil. A minimum mobility buffer of 50 percent PV was required to completely protect the miscible slug.
OSTI ID:
7299564
Journal Information:
J. Pet. Technol.; (United States), Journal Name: J. Pet. Technol.; (United States) Vol. 20; ISSN JPTJA
Country of Publication:
United States
Language:
English