Association of an acetylene with three metal atoms; new trinuclear cobalt complex. [Co atoms form 3-membered ring with 3 carbonyl groups bond to each Co atom]
Journal Article
·
· J. Am. Chem. Soc.; (United States)
- Research Organization:
- Central Experiment Station, Bureau of Mines, US Dept. of Interior and MIT
- OSTI ID:
- 7298297
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 80, Issue 24
- Country of Publication:
- United States
- Language:
- English
Similar Records
Structures of the new binary metal carbonyl Os/sub 4/(CO)/sub 15/ and (eta/sup 5/-C/sub 5/Me/sub 5/)(OC)IrOs/sub 3/(CO)/sub 11/. Clusters with three-center-two-electron metal-metal bonds
Molecular structure of a Cobalt(I) complex lacking a carbonyl ligand. A unique example of Co-N bond shortening. [((CH sub 3 ) sub 4 N)(Co(dmgBF sub 2 ) sub 2 py) where py = C sub 5 H sub 5 N and (dmgBF sub 2 ) sub 2 sup 2 minus = bis((difluoroboryl)dimethylglyoximato)]
Metal complexes of fluorophosphines. 13. Reaction of fac-(CH/sub 3/CN)/sub 3/Mo(CO)/sub 3/ with (methylamino)bis(difluorophosphine). X-ray crystal structure analysis of a novel binuclear molybdenum fluorophosphine carbonyl complex with a bridging chlorine atom: (CO)/sub 2/Mo(/sup +/-CH/sub 3/N(PF/sub 2/)/sub 2/)/sub 2/(. mu. -PF/sub 2/)(. mu. -Cl)Mo(CO)(PF/sub 2/NHCH/sub 3/)
Journal Article
·
Wed Nov 11 00:00:00 EST 1987
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:7298297
Molecular structure of a Cobalt(I) complex lacking a carbonyl ligand. A unique example of Co-N bond shortening. [((CH sub 3 ) sub 4 N)(Co(dmgBF sub 2 ) sub 2 py) where py = C sub 5 H sub 5 N and (dmgBF sub 2 ) sub 2 sup 2 minus = bis((difluoroboryl)dimethylglyoximato)]
Journal Article
·
Wed Sep 04 00:00:00 EDT 1991
· Inorganic Chemistry; (United States)
·
OSTI ID:7298297
Metal complexes of fluorophosphines. 13. Reaction of fac-(CH/sub 3/CN)/sub 3/Mo(CO)/sub 3/ with (methylamino)bis(difluorophosphine). X-ray crystal structure analysis of a novel binuclear molybdenum fluorophosphine carbonyl complex with a bridging chlorine atom: (CO)/sub 2/Mo(/sup +/-CH/sub 3/N(PF/sub 2/)/sub 2/)/sub 2/(. mu. -PF/sub 2/)(. mu. -Cl)Mo(CO)(PF/sub 2/NHCH/sub 3/)
Journal Article
·
Sun Jan 01 00:00:00 EST 1984
· Inorg. Chem.; (United States)
·
OSTI ID:7298297
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COBALT COMPLEXES
CHEMICAL PREPARATION
ALKYNES
CARBONYLS
CATALYSIS
CHEMICAL REACTIONS
DIPOLE MOMENTS
INFRARED SPECTRA
NUCLEAR MAGNETIC RESONANCE
COMPLEXES
HYDROCARBONS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
RESONANCE
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COBALT COMPLEXES
CHEMICAL PREPARATION
ALKYNES
CARBONYLS
CATALYSIS
CHEMICAL REACTIONS
DIPOLE MOMENTS
INFRARED SPECTRA
NUCLEAR MAGNETIC RESONANCE
COMPLEXES
HYDROCARBONS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
RESONANCE
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties