Photolysis of NO/sub 2/ and collisional energy transfer in the reactions O + NO. -->. NO/sub 2/ and O + NO/sub 2/. -->. NO/sub 3/
Conference
·
· Int. J. Chem. Kinet.; (United States)
OSTI ID:7291306
The photolysis of nitrogen dioxide (4 to 5 torr) at 366 nm and the collisional energy transfer of 18 different inert gases involved in combination reactions of oxygen atoms with nitric oxide and NO/sub 2/ were studied. The role of nitric anhydride in the mechanism and corresponding time dependence of the quantum yield was also evaluated. The relative collision efficiencies of each inert gas are tabulated for each reaction and are evaluated in terms of the average energies transferred per collision. A theoretical analysis of the recombination rate constants is also presented.
- Research Organization:
- Ecole Polytechnique Federale, Lausanne, Switzerland
- OSTI ID:
- 7291306
- Conference Information:
- Journal Name: Int. J. Chem. Kinet.; (United States) Journal Volume: 7:Suppl. 1
- Country of Publication:
- United States
- Language:
- English
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· Int. J. Chem. Kinet.; (United States)
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Collisional energy transfer from highly excited CS{sub 2} and SO{sub 2}
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Sat Dec 30 23:00:00 EST 1995
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Reaction NO + HO/sub 2/. -->. NO/sub 2/ + OH with OH + H/sub 2/O/sub 2/. -->. HO/sub 2/ + H/sub 2/O as an HO/sub 2/-source
Conference
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Tue Dec 31 23:00:00 EST 1974
· Int. J. Chem. Kinet.; (United States)
·
OSTI ID:7210230
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500 -- Photochemistry
500100* -- Environment
Atmospheric-- Basic Studies-- (-1989)
54 ENVIRONMENTAL SCIENCES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
DATA
EARTH ATMOSPHERE
FLUIDS
GASES
INFORMATION
KINETICS
NITROGEN COMPOUNDS
NITROGEN DIOXIDE
NITROGEN OXIDES
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL OXIDANTS
REACTION KINETICS
400500 -- Photochemistry
500100* -- Environment
Atmospheric-- Basic Studies-- (-1989)
54 ENVIRONMENTAL SCIENCES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
DATA
EARTH ATMOSPHERE
FLUIDS
GASES
INFORMATION
KINETICS
NITROGEN COMPOUNDS
NITROGEN DIOXIDE
NITROGEN OXIDES
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL OXIDANTS
REACTION KINETICS