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Physical and optical properties of Cu nanoclusters fabricated by ion implantation in fused silica

Journal Article · · Journal of Applied Physics; (United States)
DOI:https://doi.org/10.1063/1.357814· OSTI ID:7288648
 [1]; ;  [2];  [1];  [3]
  1. Department of Applied and Engineering Sciences, Vanderbilt University, Nashville, Tennessee 37235 (United States)
  2. Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37235 (United States)
  3. Surface Modification and Characterization Facility, Solid-State Physics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6038 (United States)

Cu clusters of nanometer dimensions were created by implantation of Cu ions into pure fused silica substrates at energies of 160 keV. The sizes and size distributions of the Cu clusters were measured by transmission electron microscopy, and were found to be determined by the ion-beam current during implantation. Optical-absorption spectra of these materials show the size-dependent surface plasmon resonance characteristic of noble-metal clusters. There are also significant size-dependent effects in both the nonlinear index of refraction and two-photon absorption coefficients. The distinctive variations in linear and nonlinear optical properties with Cu nanocluster sizes and size distributions affords potentially interesting possibilities for using these materials in nonlinear optical devices.

DOE Contract Number:
AC05-84OR21400
OSTI ID:
7288648
Journal Information:
Journal of Applied Physics; (United States), Journal Name: Journal of Applied Physics; (United States) Vol. 76:2; ISSN JAPIAU; ISSN 0021-8979
Country of Publication:
United States
Language:
English