Application of interferometry to simultaneous multielement atomic emission spectrometry. [Oxygen-hydrogen flame]
Journal Article
·
· Anal. Chem.; (United States)
OSTI ID:7283083
A technique for simultaneous multielement analysis based on a scanning Fabry-Perot interferometer and atomic emission is described. Detection limits are determined for various common elements using the oxygen-hydrogen flame as a test case. The results show that semitrace to trace levels in solution can be analyzed. This technique is limited to groups of elements which contain relatively few total emission lines in a certain wavelength region. Spectral interference can, in general, be eliminated by the proper choice of the interferometer spacing. Analysis of tap water and parameters essential to this optical scheme are discussed. The main advantages of this technique are the high luminosity and the ability to perform analysis in the millisecond time scale. (auth)
- Research Organization:
- Ames Lab., IA
- OSTI ID:
- 7283083
- Journal Information:
- Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 48:4; ISSN ANCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104* -- Spectral Procedures-- (-1987)
ALKALI METALS
ALKALINE EARTH METALS
BARIUM
CALCIUM
CHEMICAL ANALYSIS
CHROMIUM
ELEMENTS
EMISSION SPECTROSCOPY
INTERFERENCE
INTERFEROMETRY
LITHIUM
LUMINOSITY
MANGANESE
METALS
MULTI-ELEMENT ANALYSIS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
RUBIDIUM
SODIUM
SPECTROSCOPY
STRONTIUM
TRACE AMOUNTS
TRANSITION ELEMENTS
400104* -- Spectral Procedures-- (-1987)
ALKALI METALS
ALKALINE EARTH METALS
BARIUM
CALCIUM
CHEMICAL ANALYSIS
CHROMIUM
ELEMENTS
EMISSION SPECTROSCOPY
INTERFERENCE
INTERFEROMETRY
LITHIUM
LUMINOSITY
MANGANESE
METALS
MULTI-ELEMENT ANALYSIS
OPTICAL PROPERTIES
PHYSICAL PROPERTIES
RUBIDIUM
SODIUM
SPECTROSCOPY
STRONTIUM
TRACE AMOUNTS
TRANSITION ELEMENTS