Synthesis and characterization of rhenium metallocarboxylates

Journal Article · Thu Mar 31 23:00:00 EST 1994 · Organometallics; (United States)

DOI:https://doi.org/10.1021/om00016a008· OSTI ID:7267435

Gibson, D H; Mehta, J M; Ye, M; Richardson, J F; Mashuta, M S ^[1]

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1. Univ. of Louisville, KY (United States)

Reactions of a new metallocarboxylic acid, Cp*Re(CO)(NO)COOH (2), with Ph[sub 3]SnCl and Re(CO)[sub 4]-(PPh[sub 3])(F-BF[sub 3]) have provided the corresponding CO[sub 2]-bridged complexes Cp*Re(CO)(NO)(CO[sub 2])SnPh[sub 3] (3) and Cp*Re(CO)(NO)(CO[sub 2])Re(CO)[sub 3](PPh[sub 3]) (4), which have been structurally characterized. Complexes 3 and 4 exhibit different types of [mu][sub 2]-[eta][sup 3] bonding of the bridging CO[sub 2] ligand which can be correlated with the IR and [sup 13]C NMR spectral properties of the compounds. 15 refs., 2 figs.

• OSTI ID: 7267435
• Journal Information: Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 13:4; ISSN 0276-7333; ISSN ORGND7
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
400201* -- Chemical & Physicochemical Properties
CARBON 13
CARBON ISOTOPES
CARBOXYLIC ACIDS
CHEMICAL BONDS
CHEMICAL REACTIONS
COMPLEXES
EVEN-ODD NUCLEI
INFRARED SPECTRA
ISOTOPES
LIGANDS
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RHENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TIN COMPLEXES
TRANSITION ELEMENT COMPLEXES