Pulse radiolysis studies of uranium(VI), neptunium(VI), neptunium(V), and plutonium(VI) in aqueous perchlorate media

Journal Article · Thu Jul 15 00:00:00 EDT 1976 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100556a006· OSTI ID:7267334

Sullivan, J C; Gordon, S; Cohen, D; Mulac, W; Schmidt, K H

Reactions of several actinide (An) perchlorates with e/sub aq//sup -/ and OH radicals produced by pulse radiolysis of solutions of these compounds are reported. Kinetic data for the formation of a U(VI)--H/sub 2/O/sub 2/ complex are reported. Rate parameters for the reaction of the e/sub aq//sup -/ with various actinides have been determined and their significance discussed.

• Research Organization: Argonne National Lab., IL
• OSTI ID: 7267334
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 80:15; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
400702 -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ABSORPTION SPECTRA
ACTINIDE COMPOUNDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
CHLORINE COMPOUNDS
DECOMPOSITION
ELECTRONS
ELEMENTARY PARTICLES
FERMIONS
HALOGEN COMPOUNDS
HYDRATION
HYDROXYL RADICALS
IRRADIATION
KINETICS
LEPTONS
NEPTUNIUM COMPOUNDS
NEPTUNIUM PERCHLORATES
OXYGEN COMPOUNDS
PERCHLORATES
PLUTONIUM COMPOUNDS
PLUTONIUM PERCHLORATES
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADICALS
RADIOLYSIS
REACTION KINETICS
REDOX REACTIONS
SOLVATED ELECTRONS
SOLVATION
SPECTRA
TRANSURANIUM COMPOUNDS
URANIUM COMPOUNDS
URANIUM PERCHLORATES