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Anaerobic degradation of chloroaromatic compounds in aquatic sediments under a variety of enrichment conditions

Technical Report ·
OSTI ID:7267205

Anaerobic degradation of monochlorinated phenols and monochlorinated benzoates by a variety of aquatic sediments was compared under four enrichment conditions. A broader range of compounds was degraded in enrichments inoculated with sediment exposed to industrial effluents. Methanogenic and 1 mM BESA-amended enrichments were most likely, while nitrate and sulfate enrichments least likely, to degrade the compounds tested. Chlorophenols were more readily degraded than chlorobenzoates. However, 2-chlorophenol, 3-chlorophenol, and 3-chlorobenzoate degradation was observed most often and with equal frequency. Para-chlorinated compounds were least likely to be degraded. A relative order of ortho < meta < para was observed for onset of chlorophenol degradation, while the order for chlorobenzoate degradation was meta < ortho < para. In laboratory transfers, 2- and 3-chlorobenzoate degradation was most easily maintained, while degradation of para-chlorinated compounds was least stable.

Research Organization:
Technical Resources, Inc., Gulf Breeze, FL (USA)
OSTI ID:
7267205
Report Number(s):
PB-90-128018/XAB
Country of Publication:
United States
Language:
English