Ga atom-ethylene complex: matrix isolation ESR study
Journal Article
·
· J. Phys. Chem.; (United States)
The Ga atom-ethylene complex, Ga(C/sub 2/H/sub 4/), was generated in argon matrices and its ESR spectrum was examined. The spectral analysis revealed that the complex has a side-on structure and is held by a dative interaction between the semifilled Ga 4p/sub x/ orbital and the antibonding ..pi../sub y/* orbital of ethylene. The g tensor and the /sup 69/Ga hyperfine tensor were determined as follows: g/sub x/ = 2.0031 (6), g/sub y/ = 1.9745 (6), g/sub z/ = 2.0235 (6), A/sub x/ = 92 (1) G, A/sub y/ = -40 (1) G, and A/sub z/ = -30 (1) G.
- Research Organization:
- IBM Almaden Research Center, San Jose, CA (USA)
- OSTI ID:
- 7256289
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 92:5; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
COMPLEXES
DATA
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
ELEMENTS
ETHYLENE
EXPERIMENTAL DATA
GALLIUM
GALLIUM 69
GALLIUM ISOTOPES
HYDROCARBONS
HYPERFINE STRUCTURE
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOTOPES
MAGNETIC RESONANCE
MATRIX ISOLATION
METALS
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
RESONANCE
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
VERY LOW TEMPERATURE
400201* -- Chemical & Physicochemical Properties
ALKENES
COMPLEXES
DATA
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
ELEMENTS
ETHYLENE
EXPERIMENTAL DATA
GALLIUM
GALLIUM 69
GALLIUM ISOTOPES
HYDROCARBONS
HYPERFINE STRUCTURE
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOTOPES
MAGNETIC RESONANCE
MATRIX ISOLATION
METALS
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
RESONANCE
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
VERY LOW TEMPERATURE