CS/sup +/(A/sup 2/II/sub i/-X/sub 2/. sigma. /sup +/) chemiluminescence produced in the reaction of C/sup +/(/sup 2/P) with CS/sub 2/ at thermal energy

Journal Article · Thu Mar 10 04:00:00 EST 1988 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j100316a032· OSTI ID:7256281

Tsuji, M; Mizukami, K; Obase, H; Nishimura, Y

CS/sup +/(A/sup 2/II/sub i/-X/sup 2/..sigma../sup +/) chemiluminescence has been observed from the C/sup +/(2P) + CS/sub 2/ reaction in a flowing afterglow. The vibrational distribution of CS/sup +/(A,v' = 1-8) was nearly exponential with an effective Boltzmann temperature of 2800 +- 300 K. The average fraction of vibrational energy deposited into CS/sup +/(A) was estimated to be 0.11.

• Research Organization: Kyushu Univ., Fukuoka (Japan)
• OSTI ID: 7256281
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 92:5; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
500100 -- Environment
Atmospheric-- Basic Studies-- (-1989)
54 ENVIRONMENTAL SCIENCES
CARBON COMPOUNDS
CARBON SULFIDES
CATIONS
CHALCOGENIDES
CHARGED PARTICLES
CHEMICAL REACTIONS
CHEMILUMINESCENCE
DATA
ENERGY LEVELS
ENERGY TRANSFER
EXCITED STATES
EXPERIMENTAL DATA
INFORMATION
IONS
LUMINESCENCE
NUMERICAL DATA
REACTION INTERMEDIATES
SULFIDES
SULFUR COMPOUNDS
VIBRATIONAL STATES