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A high-resolution sup 13 C solid-state NMR study of meso-tetraphenylporphyrin and its zinc(II) complex

Journal Article · · Journal of Coordination Chemistry; (United States)
; ;  [1];  [2]
  1. Univ. of Cambridge (United Kingdom)
  2. Univ. of Aveiro (Portugal)
High-resolution {sup 13}C solid-state NMR spectra of meso-tetraphenylporphyrin (TPP) and its zinc(II) complex (ZnTPP) are assigned by reference to low-temperature solution NMR results and using {sup 1}H- {sup 13}C cross-polarization magic-angle-spinning (CP/MAS). The splittings of the signals from pyrrole carbons in TPP are attributed to kinetic solid-state states involved in the migration of the central hydrogen atom.
OSTI ID:
7252945
Journal Information:
Journal of Coordination Chemistry; (United States), Journal Name: Journal of Coordination Chemistry; (United States) Vol. 25:3; ISSN JCCMB; ISSN 0095-8972
Country of Publication:
United States
Language:
English