Cooxidation of benzyl alcohol with cumene in dimethyl sulfoxide

Journal Article · Fri Nov 01 04:00:00 EST 1985 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7251902

Opeida, I A; Dubina, V N; Shendrik, A N

This paper presents a kinetic and mechanistic study of the oxidation of benzyl alcohol and cumene and the cooxidation of these two substances in a dimethyl sulfoxide (DMSO) medium. It has been shown that the DMSO, while it is not cooxidized with the other two compounds, increases the rates of their oxidation and cooxidation. A formal kinetic analysis has been made of the process of cooxidation of benzyl alcohol with cumene in mixtures rich in the alcohol component, where the cooxidation rate is a linear function of the composition. The parameters of cooxidation of benzyl alcohol with cumene have been determined in mixtures with and without the DMSO.

• Research Organization: Institute of Physical Organic Chemistry, Ukrainian SSR Acad. of Sci., Donetsk
• OSTI ID: 7251902
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 26:3, PT. 1; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
AROMATICS
BENZYL ALCOHOL
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CUMENE
DMSO
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROXY COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
OXIDIZERS
REACTION KINETICS
SULFOXIDES