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Inhibition of the polymerization of methyl methacrylate and methyl acrylate by mixtures of chloranil with phenothiazine

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:7251813
; ;

This paper investigates the kinetic peculiarities of inhibited polymerization of methyl methacrylate and methyl acrylate in the presence of mixtures of chloranil with phenothiazine. It is shown that depending on the structure of the monomer and the concentrations of the electron donor and electron acceptor, the radicals of propagation may form complexes with chloranil or with phenothiazine at the first step of the inhibition reaction or may interact with the complex (phenothiazine to chloranil).

Research Organization:
N.V. Lomonosov Moscow Institute of Fine Chemical Technology
OSTI ID:
7251813
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 26:2,PT.1; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
AZINES
BENZOQUINONES
BINDING ENERGY
CARBOXYLIC ACID ESTERS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORANIL
COMPLEXOMETRY
COPOLYMERIZATION
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ESTERS
FERMIONS
HETEROCYCLIC COMPOUNDS
INHIBITION
KINETICS
LEPTONS
METHACRYLIC ACID ESTERS
METHYL METHACRYLATE
MOLECULAR STRUCTURE
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
PHENOTHIAZINES
PMMA
POLYACRYLATES
POLYMERIZATION
POLYMERS
POLYVINYLS
QUINONES
REACTION KINETICS
REDOX REACTIONS
VALENCE
YIELDS