Study of cyclohexane oxidation on NaX zeolite by means of IR spectroscopy under nonstationary conditions. II. Nonstationary kinetic model
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:7251781
A kinetic study has been made of the oxidation of cyclohexane on NaX zeolite under nonstationary conditions, with simultaneous recording of the IR spectra of the surface compounds, at temperatures of 473-588/sup 0/K with a 0.1-1% concentration of cyclohexane in oxygen. The diffusivity of cyclohexane into the NaX zeolite was measured at 373-453/sup 0/K. A nonstationary kinetic model of cyclohexane oxidation is proposed.
- Research Organization:
- Institute of Chemical Physics, Acad. of Sci., Moscow
- OSTI ID:
- 7251781
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:1, PT. 2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CYCLOHEXANE
CHEMICAL REACTION KINETICS
HETEROGENEOUS CATALYSIS
INFRARED SPECTRA
OXIDATION
ZEOLITES
CATALYTIC EFFECTS
ACETATES
CARBONYLS
DIFFUSION
FORMATES
HIGH TEMPERATURE
MATHEMATICAL MODELS
REACTION INTERMEDIATES
ALKANES
CARBOXYLIC ACID SALTS
CATALYSIS
CHEMICAL REACTIONS
CYCLOALKANES
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
REACTION KINETICS
SPECTRA
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CYCLOHEXANE
CHEMICAL REACTION KINETICS
HETEROGENEOUS CATALYSIS
INFRARED SPECTRA
OXIDATION
ZEOLITES
CATALYTIC EFFECTS
ACETATES
CARBONYLS
DIFFUSION
FORMATES
HIGH TEMPERATURE
MATHEMATICAL MODELS
REACTION INTERMEDIATES
ALKANES
CARBOXYLIC ACID SALTS
CATALYSIS
CHEMICAL REACTIONS
CYCLOALKANES
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
REACTION KINETICS
SPECTRA
400201* - Chemical & Physicochemical Properties