Activation and desulfurization of thiophene and benzothiophene by iron carbonyls
Journal Article
·
· Organometallics; (United States)
It is generally accepted that the sulfur heterocycles are the most refractory forms of sulfur in fossil fuels. The recent surge of interest in coordination chemistry of thiophenes is due to the growing recognition of this situation. Of the thiophenes found in fossil fuels, benzo-, and dibenzothiophene derivatives are much more prevalent than alkylthiophenes. This point is important since, as they show in this paper, the organometallic chemistries of benzothiophene and thiophene are very different.
- Research Organization:
- Univ. of Illinois, Urbana (USA)
- OSTI ID:
- 7247658
- Journal Information:
- Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 7:5; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020400 -- Petroleum-- Processing
020800 -- Petroleum-- Waste Management
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DATA
DESULFURIZATION
ENERGY
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPOUNDS
KINETICS
LATTICE PARAMETERS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYCYCLIC SULFUR HETEROCYCLES
REACTION KINETICS
SPACE GROUPS
SYNTHESIS
THIOPHENE
TRANSITION ELEMENT COMPOUNDS
020400 -- Petroleum-- Processing
020800 -- Petroleum-- Waste Management
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
CHEMICAL PREPARATION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DATA
DESULFURIZATION
ENERGY
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
INFORMATION
IRON COMPOUNDS
KINETICS
LATTICE PARAMETERS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POLYCYCLIC SULFUR HETEROCYCLES
REACTION KINETICS
SPACE GROUPS
SYNTHESIS
THIOPHENE
TRANSITION ELEMENT COMPOUNDS