Reaction of organoboranes with olefinic. cap alpha. ,. beta. -unsaturated nitro compounds

Journal Article · Mon Feb 01 04:00:00 EST 1988 · Organometallics; (United States)

DOI:https://doi.org/10.1021/om00092a040· OSTI ID:7247336

Kabalka, G W; Gai, Y Z; Goudgaon, N M; Varma, R S; Gooch, E E

The reaction of lithium triethylborohydride with nitroalkenes in the presence of borane results in the unexpected formation of N-ethylamine derivatives. Evidence supports a reaction sequence involving the 1,2-addition of triethylborane to a nitroso intermediate.

• Research Organization: Univ. of Tennessee, Knoxville (USA)
• DOE Contract Number: FG05-86ER60434
• OSTI ID: 7247336
• Journal Information: Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 7:2; ISSN ORGND
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
BORANES
BORON COMPOUNDS
CHEMICAL REACTIONS
DATA
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
NITRO COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION INTERMEDIATES