Polarization effects in collision-induced intramultiplet mixing for Ne)(2p)/sup 5/(3p)) + He
High-quality polarized-emission cross sections for the )..cap alpha..)/sub 5/ = chemically bondJ = 1,M/sub J/>..-->..)..cap alpha..)/sub 7/ and )..cap alpha..)/sub 5/..-->..)..cap alpha..)/sub 4/ transitions in the )..cap alpha..) = )(2p)/sup 5/(3p)) multiplet (lifetime 20 ns) have been measured in a crossed-beam experiment. For the )..cap alpha..)/sub 5/..-->..)..cap alpha..)/sub 7/ transition we observe a strong preference for the chemically bondM/sub J/chemically bond = 0 orientation. The small cross section for the chemically bondM/sub J/chemically bond = 1 orientation can be understood qualitatively from the model potentials of Hennecart and Masnou-Seeuws by the strong coupling to the )..cap alpha..)/sub 4/ and )..cap alpha..)/sub 6/ states (avoided crossings), which is absent for the ..cap omega.. = chemically bondM/sub J/chemically bond = 0/sup -/ molecular potentials because of the constraint of reflection symmetry.
- Research Organization:
- Physics Department, Eindhoven University of Technology, Eindhoven, The Netherlands
- OSTI ID:
- 7244348
- Journal Information:
- Phys. Rev. Lett.; (United States), Journal Name: Phys. Rev. Lett.; (United States) Vol. 57:13; ISSN PRLTA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
640304 -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
BEAMS
COLLIDING BEAMS
CROSS SECTIONS
ELECTRIC FIELDS
ELECTROMAGNETIC RADIATION
ELEMENTS
EMISSION
ENERGY DEPENDENCE
ENERGY LEVELS
ENERGY RANGE
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
FINE STRUCTURE
FLUIDS
GASES
HELIUM
INELASTIC SCATTERING
LASER RADIATION
LIFETIME
MEV RANGE
MEV RANGE 10-100
NEON
NONMETALS
P STATES
PHOTON EMISSION
POLARIZATION
RADIATIONS
RARE GASES
SCATTERING
TOTAL CROSS SECTIONS
VARIATIONS