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Polarization effects in collision-induced intramultiplet mixing for Ne)(2p)/sup 5/(3p)) + He

Journal Article · · Phys. Rev. Lett.; (United States)

High-quality polarized-emission cross sections for the )..cap alpha..)/sub 5/ = chemically bondJ = 1,M/sub J/>..-->..)..cap alpha..)/sub 7/ and )..cap alpha..)/sub 5/..-->..)..cap alpha..)/sub 4/ transitions in the )..cap alpha..) = )(2p)/sup 5/(3p)) multiplet (lifetime 20 ns) have been measured in a crossed-beam experiment. For the )..cap alpha..)/sub 5/..-->..)..cap alpha..)/sub 7/ transition we observe a strong preference for the chemically bondM/sub J/chemically bond = 0 orientation. The small cross section for the chemically bondM/sub J/chemically bond = 1 orientation can be understood qualitatively from the model potentials of Hennecart and Masnou-Seeuws by the strong coupling to the )..cap alpha..)/sub 4/ and )..cap alpha..)/sub 6/ states (avoided crossings), which is absent for the ..cap omega.. = chemically bondM/sub J/chemically bond = 0/sup -/ molecular potentials because of the constraint of reflection symmetry.

Research Organization:
Physics Department, Eindhoven University of Technology, Eindhoven, The Netherlands
OSTI ID:
7244348
Journal Information:
Phys. Rev. Lett.; (United States), Journal Name: Phys. Rev. Lett.; (United States) Vol. 57:13; ISSN PRLTA
Country of Publication:
United States
Language:
English