Optical to electrical energy conversion. Characterization of cadmium sulfide and cadmium selenide based photoelectrochemical cells. [Conversion mechanisms and efficiencies]

Journal Article · Wed Oct 27 04:00:00 EDT 1976 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00438a016· OSTI ID:7235695

Ellis, A B; Kaiser, S W; Wrighton, M S

Studies are reported on CS and CdSe based photoelectrochemical cells using aqueous sulfide or polysulfide electrolytes. The key finding is that both n-type CdS and CdSe are stabilized to photoanodic dissolution (irreversible decomposition). The reaction occurring at the photoanode (CdS or CdSe) is the oxidation of the sulfide or polysulfide. But a polysulfide electrolyte undergoes no net chemical change, since the cathode reaction is the reduction of some polysulfide species. The onset of photoresponse for CdSe and CdS based cells is near the band gap of the photoelectrode corresponding to approximately 750 nm for CdSe and approximately 520 nm for CdS. Open circuit photopotentials of up to 0.8 V for CdS and up to 0.65 V for CdSe have been observed in the polysulfide electrolyte. Overall optical to electrical energy conversion of approximately 7% for CdS at 500 nm and approximately 9% for CdSe at 632.8 nm with an output voltage of approximately 0.3 V can be realized at low light intensity. Estimated solar energy conversion efficiency for CdSe is approximately 2%.

• Research Organization: Massachusetts Inst. of Tech., Cambridge
• OSTI ID: 7235695
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 98:22; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140501* -- Solar Energy Conversion-- Photovoltaic Conversion
ANODES
CADMIUM COMPOUNDS
CADMIUM SELENIDES
CADMIUM SULFIDES
CATHODES
CHALCOGENIDES
CONVERSION
EFFICIENCY
ELECTROCHEMICAL CELLS
ELECTRODES
ELECTROLYTES
ENERGY CONVERSION
INORGANIC PHOSPHORS
OPERATION
PERFORMANCE
PHOSPHORS
PHOTOGALVANIC CELLS
SELENIDES
SELENIUM COMPOUNDS
SOLAR ENERGY CONVERSION
STABILITY
SULFIDES
SULFUR COMPOUNDS