Nuclear quadrupole resonance

Journal Article · Thu Jan 01 04:00:00 EST 1970 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1016/B978-0-12-580201-7.50014-X· OSTI ID:7228574

Schultz, H D

The subject of nuclear quadrupole resonance is reviewed. Theoretical aspects are discussed first: electric quadrupole moment, electric field gradient, nuclear quadrupole resonance, and methods for measuring quadrupole coupling constants (pure quadrupole resonance, Zeeman effect, nuclear magnetic resonance, microwave spectrum, Moessbauer spectroscopy, other techniques). Factors affecting the resonance signal include static and dynamic influences on the line width and the position of the resonance signal. Instrumentation is briefly described. The correlation of nuclear quadrupole coupling constants with molecular structure is treated. Applications to halides (Group III, Group IV, transition metals, hexahalides in heavy atoms, etc.), nitrogen quadrupole resonance, minerals (chemical and structural properties, order--disorder phenomena), and quantitative analysis are examined. 6 figures, 7 tables, 77 references. (RWR)

• Research Organization: Bureau of Mines, Morgantown, WV
• OSTI ID: 7228574
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 1; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400104 -- Spectral Procedures-- (-1987)
656000* -- Condensed Matter Physics
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CHEMICAL ANALYSIS
COUPLING CONSTANTS
CRYOGENIC FLUIDS
DOCUMENT TYPES
ELEMENTS
FLUIDS
HALIDES
HALOGEN COMPOUNDS
MEASURING METHODS
MINERALS
MOLECULAR STRUCTURE
NITROGEN
NONMETALS
NUCLEAR QUADRUPOLE RESONANCE
QUADRUPOLE MOMENTS
QUANTITATIVE CHEMICAL ANALYSIS
RESONANCE
REVIEWS
SIGNALS