Structure of chlorinated poly(vinyl chloride). III. Preparation of poly(vinyl chloride)-. beta. ,. beta. -d/sub 2/ as a model for the study of the mechanism of chlorination and of the chlorinated poly(vinyl chloride) structure
Journal Article
·
· J. Polym. Sci.; (United States)
OSTI ID:7226633
A method for the preparation of poly(vinyl chloride)-..beta..,..beta..-d/sub 2/ (PVC-..beta..,..beta..-d/sub 2/) as a model for the investigation of the mechanism of chlorination and of the CPVC structure has been suggested. The conditions of preparation of deuterated intermediates of a multistage synthesis of vinyl chloride-..beta..,..beta..-d/sub 2/ and of suspension-polymerized PVC-..beta..,..beta..-d/sub 2/ have been described including the mass balance. Malonic acid was used as the starting compound. Tacticity values of a sample of PVC-..beta..,..beta..-d/sub 2/ and its infrared and nuclear magnetic resonance (NMR) spectra are presented and compared with the data already published.
- Research Organization:
- Inst. of Macromolecular Chemistry, Prague
- OSTI ID:
- 7226633
- Journal Information:
- J. Polym. Sci.; (United States), Journal Name: J. Polym. Sci.; (United States) Vol. 14; ISSN JPSCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATION
CHLORINE
DEUTERIUM
ELEMENTS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HALOGENS
HYDROGEN ISOTOPES
INFRARED SPECTRA
ISOTOPE EFFECTS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
MAGNETIC RESONANCE
NONMETALS
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ODD-ODD NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
POLYMERS
POLYVINYLS
PVC
RESONANCE
SPECTRA
STABLE ISOTOPES
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATION
CHLORINE
DEUTERIUM
ELEMENTS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HALOGENS
HYDROGEN ISOTOPES
INFRARED SPECTRA
ISOTOPE EFFECTS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
MAGNETIC RESONANCE
NONMETALS
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ODD-ODD NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
POLYMERS
POLYVINYLS
PVC
RESONANCE
SPECTRA
STABLE ISOTOPES