Structure of chlorinated poly(vinyl chloride). III. Preparation of poly(vinyl chloride)-. beta. ,. beta. -d/sub 2/ as a model for the study of the mechanism of chlorination and of the chlorinated poly(vinyl chloride) structure

Journal Article · Thu Jan 01 00:00:00 EST 1976 · J. Polym. Sci.; (United States)

OSTI ID:7226633

Lukas, R; Kolinsky, M

A method for the preparation of poly(vinyl chloride)-..beta..,..beta..-d/sub 2/ (PVC-..beta..,..beta..-d/sub 2/) as a model for the investigation of the mechanism of chlorination and of the CPVC structure has been suggested. The conditions of preparation of deuterated intermediates of a multistage synthesis of vinyl chloride-..beta..,..beta..-d/sub 2/ and of suspension-polymerized PVC-..beta..,..beta..-d/sub 2/ have been described including the mass balance. Malonic acid was used as the starting compound. Tacticity values of a sample of PVC-..beta..,..beta..-d/sub 2/ and its infrared and nuclear magnetic resonance (NMR) spectra are presented and compared with the data already published.

• Research Organization: Inst. of Macromolecular Chemistry, Prague
• OSTI ID: 7226633
• Journal Information: J. Polym. Sci.; (United States), Vol. 14
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHLORINATED ALIPHATIC HYDROCARBONS
CHEMICAL REACTIONS
DEUTERIUM
ISOTOPE EFFECTS
PVC
CHLORINATION
CHLORINE
INFRARED SPECTRA
LABELLED COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
ELEMENTS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HALOGENS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC POLYMERS
POLYMERS
POLYVINYLS
RESONANCE
SPECTRA
STABLE ISOTOPES
400302* - Organic Chemistry- Isotope Effects- (-1987)