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U.S. Department of Energy
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Antireflection coatings for calcium fluoride laser windows for 5. 3 microns. Final technical report, 1 Oct 1974--1 Mar 1976

Technical Report ·
OSTI ID:7223183
Four distinct antireflection (AR) coatings and half-wave coatings of their constituent coating materials were evaluated for 5.3 microns on CaF/sub 2/ and BaF/sub 2/ substrates. The coating materials were lead and strontium fluoride, thorium tetrafluoride, and zirconium dioxide. The coatings were evaluated with regard to absorption, peak transmission, bandwidth, redisual strain, and adhesion. A PbF/sub 2//ThF/sub 4/ AR design had an absorption per surface less than .05%. The absorption of ZrO/sub 2/ is excessive at 5.3. All AR designs passed the scotch tape adhesion test. The index of SrF/sub 2/ in thin film form is lower than the bulk value. In half-wave coatings of SrF/sub 2/ an index as low as 1.22 was observed. Bandwidths of three AR designs were 0.5 microns or greater. Absorptions of half-wave coatings at 1.06 and 3.8 microns indicate that further development will be required for these wavelengths. Absorption measurements for the PbF/sub 2//ThF/sub 4/ design for CaF/sub 2/ windows coated on both sides are reported for 5.3, 3.8, and 2.8 microns. The windows absorbed 0.04%, 0.2%, and 0.5%, respectively. Some designs were plaqued with stress-induced birefringence in the visible spectra which did not adversely affect the transmission in the ir. The PbF/sub 2/, ThF/sub 4/, and ZrO/sub 2/ coatings did not show residual strain. The absorption measurements obtained on three different calorimeters are compared.
Research Organization:
Air Force Materials Lab., Wright-Patterson AFB, OH (USA)
OSTI ID:
7223183
Report Number(s):
AD-A-033103; AFML-TR-76-103
Country of Publication:
United States
Language:
English