Thermal reactions of organic nitrogen compounds. II. 1-n-butylpyrrole
Journal Article
·
· J. Phys. Chem.; (United States)
OSTI ID:7219953
Thermal reactions of 1-n-butylpyrrole were investigated in the 460 to 570/sup 0/ range by a flow method and in the 360 to 400/sup 0/ range by a static method. 1-n-Butylpyrrole isomerized to 2-n-butylpyrrole which then isomerized by a reversible reaction to 3-n-butylpyrrole. The Arrhenius equation for the isomerization of 1-n-butylpyrrole is given. The 2- and 3-n-butylpyrroles decompose to form pyrrole, 2- and 3-methylpyrroles, 2- and 3-ethylpyrroles, 2- and 3-vinylpyrroles, pyridines, and hydrocarbons.
- Research Organization:
- Bureau of Mines, Laramie, WY
- OSTI ID:
- 7219953
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 62:12; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
04 OIL SHALES AND TAR SANDS
040500 -- Oil Shales & Tar Sands-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AZOLES
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
ENERGY SOURCES
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
ISOMERIZATION
MINERAL OILS
OILS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OTHER ORGANIC COMPOUNDS
PYRROLES
SHALE OIL
SYNTHETIC FUELS
SYNTHETIC PETROLEUM
040500 -- Oil Shales & Tar Sands-- Properties & Composition
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AZOLES
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
ENERGY SOURCES
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
ISOMERIZATION
MINERAL OILS
OILS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OTHER ORGANIC COMPOUNDS
PYRROLES
SHALE OIL
SYNTHETIC FUELS
SYNTHETIC PETROLEUM