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Influence of macrobenthos on chemical diagenesis of marine sediments

Technical Report ·
DOI:https://doi.org/10.2172/7218600· OSTI ID:7218600
Diagenetic reactions involving the decomposition of organic matter and the dissolution, mobilization, and reprecipitation of metals sensitive to oxidation-reduction reactions, are most intense and rapid in the upper 1 m and especially the upper 10 cm of marine sediment. It is in this upper zone where most benthic organisms live and interact with sediments and where exchange rates of dissolved and particulate material between sediment and overlying water are largely determined. In Long Island Sound, U.S.A., both spatial and temporal trends in sediment chemistry and the flux of material out of the bottom demonstrate the control of diagenesis by bottom fauna. /sup 234/Th//sup 238/U disequilibrium studies demonstrate that particle reworking rates near the sediment-water interface vary both temporally and spatially in the Sound. The most rapid reworking occurs in protobranch-inhabited bottom areas as do the highest /sup 234/Th inventories. Excess /sup 234/Th profiles in the sediment allow determination of the rates of selected diagenetic reactions, such as Mn/sup + +/ production, near the sediment surface. Both the /sup 234/Th disequilibrium and flux measurements indicate that intra-estuarine redistribution of metals continually takes place.
Research Organization:
Yale Univ., New Haven, CT (USA). Dept. of Geology and Geophysics
DOE Contract Number:
EY-76-S-02-3573
OSTI ID:
7218600
Report Number(s):
COO-3573-21
Country of Publication:
United States
Language:
English