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Title: Working fluid and cycle selection criteria for binary geothermal power plants with resource temperatures in the range of 220/sup 0/F to 400/sup 0/F

Technical Report ·
OSTI ID:7213980

Binary cycles using refrigerants as working fluids are an effective means of developing geothermal resources for power production. In order to maximize the utilization of the geothermal fluid resource over a temperature range of from 220/sup 0/F to 400/sup 0/F, a study was performed to optimize plant design with respect to working fluid and thermodynamic cycle. Additionally, system variations due to tolerances applied to key plant input factors are included for each optimum fluid-cycle combination. Four working fluids were considered in this study: isobutane, pentane, propane and Genetron 31/114 (an azeotrope of Genetron 31 and Genetron 114 developed by Allied Chemical Corporation). Isobutane, pentane, and propane are hydrocarbons, whereas Genetron 31/114 is a halogen. The parametric studies indicated that hydrocarbons were better working fluids for the binary system than were halogens. Genetron's behavior was similar to that of isobutane's but never equaled its performance. It is, however, nonexplosive, noncombustible, and relatively nontoxic, whereas the hydrocarbons are explosively combustible, and highly toxic. At some trade-off point, then, system safety may become more important than optimum cycle performance. The propane cycles controlled the optimum performance for g.f. temperatures of 220/sup 0/F to 280/sup 0/F. For a g.f. temperature range of 300/sup 0/F to 360/sup 0/F the isobutane cycles performed highest, and for g.f. temperatures of 380/sup 0/F to 400/sup 0/F, the pentane cycles were the most effective. For temperatures near the change of control points for the fluids, a mixture of fluids is recommended. The effectiveness of the system would thus be protected in case of resource degradation.

Research Organization:
Idaho Coll., Caldwell (USA). Snake River Regional Studies Center
DOE Contract Number:
EY-76-C-07-1570
OSTI ID:
7213980
Report Number(s):
TREE-1108
Country of Publication:
United States
Language:
English