Calculation of the ignition delay times for methane--oxygen--nitrogen dioxide--argon mixtures. [NO/sub 2/ effect on ignition delay times]
Journal Article
·
· Combust. Flame; (United States)
The experimental ignition delay values of methane-oxygen-argon-nitrogen dioxide mixtures published recently are confirmed and explained with the help of calculated ignition delay data. Calculation was done using a computer program with 38 reactions whose values were taken from the literature. Only two of these reactions were iteratively fitted and their rates were found to be 2.4 x 10/sup 11/ cc/mole sec for CH/sub 3/ + NO/sub 2/ ..-->.. NO + CH/sub 3/O and 1.0 x 10/sup 11/ cc/mole sec for the CH/sub 3/O + O/sub 2/ ..-->.. CH/sub 2/O + HO/sub 2/ reaction.
- Research Organization:
- Technion-Israel Inst. of Tech., Haifa
- OSTI ID:
- 7209934
- Journal Information:
- Combust. Flame; (United States), Journal Name: Combust. Flame; (United States) Vol. 28:3; ISSN CBFMA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090110* -- Hydrocarbon Fuels-- Properties-- (1979-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800 -- Combustion
Pyrolysis
& High-Temperature Chemistry
ALKANES
ARGON
CALCULATION METHODS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
COMBUSTION KINETICS
COMPUTER CALCULATIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROCARBONS
IGNITION
INHIBITION
KINETICS
METHANE
NITROGEN COMPOUNDS
NITROGEN DIOXIDE
NITROGEN OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
RARE GASES
REACTION KINETICS
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800 -- Combustion
Pyrolysis
& High-Temperature Chemistry
ALKANES
ARGON
CALCULATION METHODS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
COMBUSTION KINETICS
COMPUTER CALCULATIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROCARBONS
IGNITION
INHIBITION
KINETICS
METHANE
NITROGEN COMPOUNDS
NITROGEN DIOXIDE
NITROGEN OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN
OXYGEN COMPOUNDS
RARE GASES
REACTION KINETICS