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Lattice location studies of gases in metals

Journal Article · · Adv. Chem. Ser.; (United States)
Ion channeling and nuclear microanalysis techniques can determine the crystallographic lattice locations of implanted or dissolved gases in single crystal metals. Ion-induced nuclear reaction, x-ray, or backscattering measurements of channeling angular yield distributions along specific axes and planes clearly indicate lattice locations of gases for high symmetry sites. Interstitial and substitutional sites can be clearly distinguished. Light gas atoms such as hydrogen and oxygen occupy well defined interstitial positions, whereas heavier noble gas atoms do not occupy well defined interstitial or substitutional sites. In bcc metals deuterium is located in tetrahedral sites in W, Cr, and Mo at low temperature and in distorted octahedral sites in Cr and Mo at higher temperatures. For implanted He in W, multiple He atoms are trapped by lattice vacancies.
Research Organization:
Sandia Labs., Albuquerque, NM
OSTI ID:
7208770
Journal Information:
Adv. Chem. Ser.; (United States), Journal Name: Adv. Chem. Ser.; (United States) Vol. 14:158; ISSN ADCSA
Country of Publication:
United States
Language:
English