Effect of high pressure on the excess electron mobility in nonpolar liquids

Conference · Tue Dec 31 23:00:00 EST 1985

OSTI ID:7204090

Nishikawa, M; Nakagawa, K; Itoh, K; Munoz, R; Holroyd, R A; Fueki, K

Excess electron mobilities were measured in n-pentane, cyclopentane, n-hexane, 3-methylpentane, 2,2-dimethylbutane(DMB), 2,2,4-trimethylpentane(TMP) and tetramethylsilane(TMS) over the range 0.1 to 250 MPa and 20 to 120/sup 0/C. For the first four liquids the mobility decreases with pressure at all temperatures studied. For 2,2-DMB and 2,2,4-TMP the mobility increases with increasing pressure at low temperatures but decreases with pressure at high temperatures. For TMS the mobility decreases with pressure only slightly at all temperatures. These results are compared with currently available theoretical models. 10 refs., 1 fig.

• Research Organization: Brookhaven National Lab., Upton, NY (USA); Tokyo Univ. (Japan). Dept. of Pure and Applied Sciences; Nagoya Univ. (Japan). Dept. of Synthetic Chemistry
• DOE Contract Number: AC02-76CH00016
• OSTI ID: 7204090
• Report Number(s): BNL-38802; CONF-860980-1; ON: DE87002154
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
DIELECTRIC MATERIALS
ELECTRON MOBILITY
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
MATERIALS
MOBILITY
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
PARTICLE MOBILITY
PRESSURE EFFECTS
SILANES
SILICON COMPOUNDS
TEMPERATURE EFFECTS