Correlation equation for calculating the dissociation constants of 1-1 electrolytes in higher alcohols over a wide temperature range

Journal Article · Thu Feb 20 04:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7203156

V'yunnik, I N; Bulavin, V I

This paper attempts to obtain, on the basis of experimentally determined dissociation constants for lithium, sodium, and potassium iodides in alcohols from amyl to nonyl at temperatures of the range 278-458 K, a simple empirical equation for calculating the dissociation of constants, with an error not exceeding 10% on the concentration of monomeric molecules in higher alcohols; this is done on the basis of known linear dependence of the difference in the logarithms of the dissociation constants found experimentally and calculated by methods due to Sukhotin, Fuoss, Bjerrum, and Ebeling.

• Research Organization: A.M. Gor'kii Khar'kov State Univ.
• OSTI ID: 7203156
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:9,PT.1; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPOUNDS
CORRELATIONS
DIAGRAMS
DISSOCIATION
DISSOCIATION HEAT
ELECTROLYTES
ENTHALPY
EQUATIONS
HALIDES
HALOGEN COMPOUNDS
HEXANOLS
HYDROXY COMPOUNDS
INORGANIC PHOSPHORS
IODIDES
IODINE COMPOUNDS
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM IODIDES
ORGANIC COMPOUNDS
PENTANOLS
PHOSPHORS
PHYSICAL PROPERTIES
POTASSIUM COMPOUNDS
POTASSIUM IODIDES
QUANTITY RATIO
REACTION HEAT
SODIUM COMPOUNDS
SODIUM IODIDES
SOLVATION
TEMPERATURE DEPENDENCE
THERMODYNAMIC PROPERTIES