Effect of substituent groups on the interaction of benzene with Ni(111)
Journal Article
·
· Langmuir; (USA)
OSTI ID:7201313
- Princeton Univ., NJ (USA)
The adsorption and reaction of aniline, phenol, methoxybenzene, benzonitrile, chlorobenzene, nitrosobenzene, nitrobenzene, and benzaldehyde were studied on Ni(111) groups to elucidate the role of substituent groups in adsorption and reaction of substituted benzenes. Temperature-programmed reaction (TPR) and reflection absorption infrared spectroscopy were used to characterize modes of bonding and reaction paths. The absorption bonds were also modeled by using the semiempirical intermediate neglect of differential overlap technique (INDO) with a 19 nickel atom cluster having the symmetry of the (111) surface.
- OSTI ID:
- 7201313
- Journal Information:
- Langmuir; (USA), Journal Name: Langmuir; (USA) Vol. 5:6; ISSN LANGD; ISSN 0743-7463
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORPTION
AROMATICS
BENZENE
DATA
DATA ANALYSIS
ELEMENTS
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
INFRARED SPECTRA
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
NICKEL
NUMERICAL DATA
ORGANIC COMPOUNDS
REACTIVITY
SORPTION
SPECTRA
SURFACE PROPERTIES
TRANSITION ELEMENTS
360104 -- Metals & Alloys-- Physical Properties
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORPTION
AROMATICS
BENZENE
DATA
DATA ANALYSIS
ELEMENTS
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
INFRARED SPECTRA
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
NICKEL
NUMERICAL DATA
ORGANIC COMPOUNDS
REACTIVITY
SORPTION
SPECTRA
SURFACE PROPERTIES
TRANSITION ELEMENTS