Volume effects in the decay of free radicals in organic crystals. [cobalt 60 gamma radiation]

Journal Article · Sun Sep 01 00:00:00 EDT 1991 · Journal of Solid State Chemistry; (United States)

DOI:https://doi.org/10.1016/0022-4596(91)90214-3· OSTI ID:7200701

Markaryan, R E; Kovarskii, A L; Tshetinin, V G ^[1]

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1. Inst. of Chemical Physics, Moscow (Russian Federation)

The decay kinetics of the free radicals produced by {gamma}-irradiation of single crystals of organic dicarboxylic acids is studied at hydrostatic pressures up to 200 MPa. Correlation is established between the reaction's activation parameters (V{sup *} and E{sup *}) and the crystals macrocharacteristics - the compressibility and thermal expansion coefficients. A common equation is proposed to describe the variation of the radical decay rate constant with temperature and pressure in malonic, succinic, adipic, glutaric, suberic, and sebacic acids.

• OSTI ID: 7200701
• Journal Information: Journal of Solid State Chemistry; (United States), Journal Name: Journal of Solid State Chemistry; (United States) Vol. 94:1; ISSN JSSCB; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400700* -- Radiochemistry & Nuclear Chemistry
ACTIVATION ENERGY
ADIPIC ACID
ANNEALING
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CARBOXYLIC ACIDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COBALT 60
COBALT ISOTOPES
COMPRESSIBILITY
CRYSTALS
DATA
DICARBOXYLIC ACIDS
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
ENERGY
EXPANSION
EXPERIMENTAL DATA
GAMMA RADIATION
GLUTARIC ACID
HEAT TREATMENTS
HIGH PRESSURE
INFORMATION
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
IONIZING RADIATIONS
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
KINETICS
MAGNETIC RESONANCE
MALONIC ACID
MATHEMATICAL MODELS
MECHANICAL PROPERTIES
MEDIUM PRESSURE
MINUTES LIVING RADIOISOTOPES
MONOCRYSTALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC ACIDS
ORGANIC COMPOUNDS
PRESSURE DEPENDENCE
RADIATIONS
RADICALS
RADIOISOTOPES
REACTION KINETICS
RESONANCE
SEBACIC ACID
SUCCINIC ACID
TEMPERATURE EFFECTS
THERMAL EXPANSION
VERY HIGH PRESSURE
YEARS LIVING RADIOISOT