Formation of 1,4- and 1,5-regioisomers of triazolines in reactions of 2-ethoxyethyl azide with monosubstituted ethylenes

Journal Article · Mon Nov 30 23:00:00 EST 1987 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00486914· OSTI ID:7200123

Lanovaya, G A; Mishchenko, V F; Korniets, E D

The structural specificity of the reactions of 2-ethoxyethyl azide with alkenes RCH=CH/sub 2/ (R = CH/sub 2/C/sub 6/H/sub 5/, CH/sub 2/OC/sub 6/H/sub 13/, CH(OC/sub 2/H/sub 5/)/sub 2/, C/sub 6/H/sub 5/) was studied. The formation of 1,4- and 1,5-substituted triazolines and the high stabilities of the latter were demonstrated by PMR spectroscopy, data from gas-liquid chromatography (GLC), and the kinetics of thermolysis.

• Research Organization: Siberian Technological Institute, Krasnoyarsk (USSR)
• OSTI ID: 7200123
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 23:6; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKENES
AZIDES
AZINES
AZOLES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHROMATOGRAPHY
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
J-J COUPLING
KINETICS
MULTIPLETS
NITROGEN COMPOUNDS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYROLYSIS
REACTION KINETICS
SEPARATION PROCESSES
SPECTRA
THERMOCHEMICAL PROCESSES
TRIAZINES
TRIAZOLES