Reaction of tellurimides with thiourea

Journal Article · Tue Oct 20 00:00:00 EDT 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7200005

Naddaka, V I; Avanesyan, K V; Cherkinskaya, M L; Minkin, V I

The authors establish that N-(p-tolylsulfonyl)di(p-methoxyphenyl)tellurimide, N-(trichloroacetyl)di(p-methoxyphenyl)tellurimide, and N-(phenylsulfonyl)diphenyltellurimide readily oxidize thiourea to cyanamide. The reaction products also include diaryl tellurides, the corresponding amides, and sulfur. The reaction path is attributed to the fact that thiourea participates in the thiol form. Infrared spectra are analyzed.

• Research Organization: M. A. Suslov Rostov State Univ. (USSR)
• OSTI ID: 7200005
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:5; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
AMIDES
ANTITHYROID DRUGS
CARBONIC ACID DERIVATIVES
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CYANAMIDES
DRUGS
ELEMENTS
ENERGY
HORMONE ANTAGONISTS
IMIDES
INFRARED SPECTRA
KINETICS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
REACTION KINETICS
SPECTRA
SULFUR
SYNTHESIS
TELLURIUM COMPOUNDS
THIOUREA
THIOUREAS
YIELDS