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Title: Argon composition of metamorphic fluids. Implications for [sup 40]Ar/[sup 39] geochronology

Journal Article · · Geological Society of America, Bulletin; (United States)

The concentration and isotopic composition of argon trapped in fluid inclusions within a mylonitic amphibolite were determined by combining electron microprobe, [sup 40]Ar/[sup 39] Ar laser microprobe, and fluid inclusion analyses on the same samples. In our study, fluid in inclusions formed during ductile deformation was probably derived locally from the Paleozoic, Caledonian sequences, whereas brines, emplaced in cross-cutting fractures, were derived from Proterozoic footwall rocks several kilometers from the mylonite. By utilizing [sup 38]Ar[sub Cl] to correct for [open quotes]excess [sup 40]Ar,[close quotes] we estimate a 370 Ma closure age for the amphibole, which is distinctly younger than the 440-480 Ma plateau ages indicated by step-heating spectra. The [open quotes]excess [sup 40]Ar[close quotes] responsible for the anomalous plateaus probably resulted from diffusive re-equilibration of the amphibole with the fluids present during ductile deformation of the mylonite. The significantly younger cooling age determined by our method is concordant with ages determined from more recent geochronological studies in the region. These ages indicate that the western gneiss terrain, in our study area, records deformation and cooling associated with Siluro-Devonian tectonothermal metamorphism rather than an earlier Caledonian tectonism as proposed in previous [sup 40]Ar/[sup 39]Ar investigators. 46 refs., 8 figs.

DOE Contract Number:
FG02-91ER14197
OSTI ID:
7198613
Journal Information:
Geological Society of America, Bulletin; (United States), Vol. 106:7; ISSN 0016-7606
Country of Publication:
United States
Language:
English

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