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Diode laser ignition of high explosives and pyrotechnics

Conference ·
OSTI ID:7197548
Thermal ignition of the explosive CP (2-(5-cyanotetrazolato)pentaamine cobalt (III) perchlorate) and of the pyrotechnic Ti/KCl0/sub 4/ has been achieved using a (GaAl)As diode laser that emitted 1 watt of optical power from the end of a 100/minus/..mu..m core fiber optic to which it was coupled. The wavelength of the emitted light was near 820 nm. Approximate ignition thresholds were obtained for pulse widths of between 2 and 10 ms. For a 10/minus/ms pulse width, pure CP required /approximately/6.7 mJ of energy for ignition whereas pure Ti/KC10/sub 4/ required only /approximately/3 mJ. Dopants such as carbon black, graphite and a laser dye were added in small concentrations to enhance light absorption and thereby reduce the ignition theshold. Their effects as well as those of powder density, particle size and spot size of the incident light on ignition threshold are described. 9 refs., 7 figs., 3 tabs.
Research Organization:
Sandia National Labs., Albuquerque, NM (USA)
DOE Contract Number:
AC04-76DP00789
OSTI ID:
7197548
Report Number(s):
SAND-87-3032C; CONF-880750-4; ON: DE88008771
Country of Publication:
United States
Language:
English