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A new stable perfluoroalkyl radical

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:7194422

This paper uses ESR spectroscopy to study the radical formed upon the gamma-irradiation of liquid perfluoro-methyl-2-pentene (PMP). The ESR spectrum of this radical shows a well resolved doublet of triplets with splitting 6.2 and 1.5 mT with additional splitting of each component by 0.25 mT. This ESR corresponds to a radical formed upon the addition of a radical r, in particlular, CF/sub 3/ to PMP.

Research Organization:
Institute of Chemical Physics, Acad. of Sci., Chernogolovka
OSTI ID:
7194422
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:7,PT.2; ISSN BACCA
Country of Publication:
United States
Language:
English