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Reactions in the system HfO/sub 2/-SrO, HfO/sub 2/-BaO, and ZrO/sub 2/-BaO in high HfO/sub 2/ or ZrO/sub 2/ regions

Journal Article · · Inorg. Mater. (Engl. Transl.); (United States)
OSTI ID:7192622
The objective of this work was to study phase equilibria in the systems HfO/sub 2/-SrO, HfO/sub 2/-BaO, and ZrO/sub 2/-BaO in the 0 to 50 mole% SrO or BaO range and between 1600 and 2800/sup 0/C with the aid of high-temperature calcining and quenching methods. The samples' phase composition was determined by x-ray, microstructural, and petrographic methods. Samples calcined and melted in the solar furnace were analyzed by x-ray diffraction at room temperature on a DRON-1.5 diffractometer with Cu-K/sub ..cap alpha../ radiation and a Ni filter. Refractive indices were measured in high-refraction immersion liquids and in sulfur and selenium alloys. They form characteristic narrow solid solution regions based on the monoclinic, tetragonal, and cubic modifications of HfO/sub 2/(ZrO/sub 2/).
OSTI ID:
7192622
Journal Information:
Inorg. Mater. (Engl. Transl.); (United States), Journal Name: Inorg. Mater. (Engl. Transl.); (United States) Vol. 23:9; ISSN INOMA
Country of Publication:
United States
Language:
English