Crystal and molecular structure of the trinuclear mixed-valence iron cluster (Fe/sub 3/-. mu. /sub 3/-O(CCl/sub 3/COO)/sub 6/(CH/sub 3/OH)/sub 3/) x 1. 5H/sub 2/O. Fast electron transfer
Journal Article
·
· Sov. J. Coordinat. Chem.; (United States)
OSTI ID:7192125
The structure has been determined by x-ray diffraction analysis at 300/sup 0/K. The carboxylato bridges have the usual geometry. One special feature of the crystal structure, which may be defined as disordering of the outer-sphere water molecules between two positions and which also specifies the placement of both types of CCl/sub 3/ groups in two positions, along with the symmetric equivalence of the (FeO/sub 6/) octahedrons provides a structural basis for the fast transfer of an electron around the system of three centers detected by gamma-resonance spectroscopy.
- OSTI ID:
- 7192125
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 13:8; ISSN SJCCD
- Country of Publication:
- United States
- Language:
- English
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·
OSTI ID:6078063
Related Subjects
36 MATERIALS SCIENCE
360602* -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
656002 -- Condensed Matter Physics-- General Techniques in Condensed Matter-- (1987-)
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ACETIC ACID
BINDING ENERGY
CARBOXYLIC ACIDS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
ELECTRON TRANSFER
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
GAMMA SPECTRA
IRON COMPLEXES
LATTICE PARAMETERS
LEPTONS
LIFETIME
MOESSBAUER EFFECT
MOLECULAR STRUCTURE
MONOCARBOXYLIC ACIDS
ORDER PARAMETERS
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
SCATTERING
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPLEXES
VALENCE
X-RAY DIFFRACTION
360602* -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
656002 -- Condensed Matter Physics-- General Techniques in Condensed Matter-- (1987-)
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ACETIC ACID
BINDING ENERGY
CARBOXYLIC ACIDS
COHERENT SCATTERING
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIFFRACTION
ELECTRON TRANSFER
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
GAMMA SPECTRA
IRON COMPLEXES
LATTICE PARAMETERS
LEPTONS
LIFETIME
MOESSBAUER EFFECT
MOLECULAR STRUCTURE
MONOCARBOXYLIC ACIDS
ORDER PARAMETERS
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
SCATTERING
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPLEXES
VALENCE
X-RAY DIFFRACTION