Heterogeneous charge transfer rates of the ferrocene oxidation in sulfolane. [In sulfolane]
Journal Article
·
· J. Electrochem. Soc.; (United States)
- Sandia Labs., Albuquerque, NM
Large deviations were found between predicted and observed rates of charge transfer for ferrocene oxidation in sulfolane; the measured rates were low. Reduction rates of nitrobenzene in sulfolane were also of the same order of magnitude. It is suggested that similar retardation might occur in other structured solvents such as DMSO or hexamethylphosphoamide. (DLC)
- OSTI ID:
- 7190878
- Journal Information:
- J. Electrochem. Soc.; (United States), Journal Name: J. Electrochem. Soc.; (United States) Vol. 123:5; ISSN JESOA
- Country of Publication:
- United States
- Language:
- English
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Electrochemistry of nitrobenzene and p-nitrobenzaldehyde studied by transmission spectroelectrochemical methods in sulfolane
Technical Report
·
Sat Oct 01 00:00:00 EDT 1977
·
OSTI ID:5279410
Liquid-liquid equilibria for the ternary systems sulfolane + octane + benzene, sulfolane + octane + toluene and sulfolane + octane + p-xylene
Journal Article
·
Tue Feb 28 23:00:00 EST 1995
· Journal of Chemical and Engineering Data
·
OSTI ID:43100
Electrochemistry of nitrobenzene and p-nitrobenzaldehyde studied by transmission spectroelectrochemical methods in sulfolane
Journal Article
·
Wed Dec 01 23:00:00 EST 1976
· J. Phys. Chem.; (United States)
·
OSTI ID:7336582
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CHARGE TRANSPORT
CHEMICAL REACTIONS
COMPLEXES
DIENES
FERROCENE
HYDROCARBONS
IRON COMPLEXES
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDATION
POLYENES
REDUCTION
SOLVENTS
TRANSITION ELEMENT COMPLEXES
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CHARGE TRANSPORT
CHEMICAL REACTIONS
COMPLEXES
DIENES
FERROCENE
HYDROCARBONS
IRON COMPLEXES
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SOLVENTS
OXIDATION
POLYENES
REDUCTION
SOLVENTS
TRANSITION ELEMENT COMPLEXES