Optical and x-ray single crystal studies of the monoclinic in equilibrium tetragonal transition in ZrO/sub 2/

Conference · Thu Jan 01 04:00:00 EST 1976 · J. Am. Ceram. Soc.; (United States)

OSTI ID:7176473

Buljan, S T; McKinstry, H A; Stubican, V S

The monoclinic reversible tetragonal phase transition in ZrO/sub 2/ single crystals was studied at temperature by transmission optical microscopy and x-ray diffraction techniques. A series of time-lapse photographs illustrated the relations between the events that occur during the transition. The events themselves were recognized by direct observation using a high-temperature microscope stage and by scrutiny of several high-temperature Laue photographs. During heating the monoclinic phase transforms to the tetragonal by the motion of an interface parallel to the (100)/sub m/ plane; simultaneous twinning also occurs behind the advancing interface. The tetragonal phase is usually twinned on the (1 anti 1 2)/sub bct/ or (anti 1 1 2)/sub bct/ plane, and the extent of twinning is influenced by the heating rate. Cooling transforms the untwinned tetragonal form into a twinned monoclinic form with the orientation of the monoclinic twins parallel to the trace of the (001)/sub m/ plane when observations are made in the (100)/sub m/ plane. Transformation of a twinned tetragonal crystal results in twins on the (110)/sub m/ and (001)/sub m/ planes. Orientation relations in the ZrO/sub 2/ transformation are: (100)/sub m/ parallel (110)/sub bct/, (010)/sub m/ parallel (001)/sub bct/, and by the virtue of twinning, (100)/sub m/ parallel (110)/sub bct/, (001)/sub m/ parallel (001)/sub bct/. During cooling the same topotaxial relations are maintained. 8 figures.

• Research Organization: Pennsylvania State Univ., University Park
• OSTI ID: 7176473
• Conference Information: Journal Name: J. Am. Ceram. Soc.; (United States) Journal Volume: 59:7/8
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360202* -- Ceramics
Cermets
& Refractories-- Structure & Phase Studies
CHALCOGENIDES
COOLING
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CRYSTALS
HEATING
MICROSCOPY
MONOCLINIC LATTICES
MONOCRYSTALS
ORIENTATION
OXIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
PHOTOGRAPHY
TETRAGONAL LATTICES
TRANSITION ELEMENT COMPOUNDS
TWINNING
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES