Crystal structure of chloryl tetrafluoroborate ClO/sub 2//sup +/BF/sub 4//sup -/ at -120/sup 0/C
Journal Article
·
· Dokl. Phys. Chem. (Engl. Transl.); (United States)
OSTI ID:7172320
The authors have synthesized and examined chloryl tetrafluoroborate, which is formed by the reaction of boron trifluoride with chlorine trifluoride in the presence of traces of water. A single crystal suitable for use was obtained by zone melting at -20/sup 0/C, zone traverse rate 0.6 mm/h. The crystals are monoclinic, and at -120/sup 0/C: a = 5.427(3), b = 8.517(5), c = 9.446(5) A, ..beta.. = 97.97(4)/sup 0/, V = 432.4(3) A/sup 3/, Z = 4, space group Cc. The data indicate that the ClF/sub 2//sup +/BF/sub 4//sup -/ is hydrolyzed by water adsorbed on the capillary, which results in ClO/sub 2//sup +/BF/sub 4//sup -/; it has been shown that this compound is formed under analogous conditions in the reaction of ClF/sub 3/ and BF/sub 3/.
- Research Organization:
- N. S. Kurnakov Institute of General and Inorganic Chemistry, Moscow (USSR)
- OSTI ID:
- 7172320
- Journal Information:
- Dokl. Phys. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Phys. Chem. (Engl. Transl.); (United States) Vol. 293:4-6; ISSN DKPCA
- Country of Publication:
- United States
- Language:
- English
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· Organometallics
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OSTI ID:315988
Fluoride ion affinities of GeF/sub 4/ and BF/sub 3/ from thermodynamic and structural data for (SF/sub 3/)/sub 2/GeF/sub 6/, ClO/sub 2/GeF/sub 5/, and ClO/sub 2/BF/sub 4/
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Related Subjects
36 MATERIALS SCIENCE
360602* -- Other Materials-- Structure & Phase Studies
ANIONS
BORON COMPOUNDS
BORON FLUORIDES
CATIONS
CHARGE DISTRIBUTION
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
CHLORINE FLUORIDES
COHERENT SCATTERING
COMPUTERIZED SIMULATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CRYSTALLIZATION
CRYSTALS
DECOMPOSITION
DIFFRACTION
ELECTRON DENSITY
ELECTRONIC STRUCTURE
FLUORIDES
FLUORINE COMPOUNDS
FLUOROBORATES
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROLYSIS
IONIC CRYSTALS
IONS
LEAST SQUARE FIT
LYSIS
MAXIMUM-LIKELIHOOD FIT
MELTING
MONOCLINIC LATTICES
MONOCRYSTALS
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
SCATTERING
SIMULATION
SOLVOLYSIS
VALENCE
WATER
X-RAY DIFFRACTION
ZONE MELTING
360602* -- Other Materials-- Structure & Phase Studies
ANIONS
BORON COMPOUNDS
BORON FLUORIDES
CATIONS
CHARGE DISTRIBUTION
CHARGED PARTICLES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
CHLORINE FLUORIDES
COHERENT SCATTERING
COMPUTERIZED SIMULATION
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CRYSTALLIZATION
CRYSTALS
DECOMPOSITION
DIFFRACTION
ELECTRON DENSITY
ELECTRONIC STRUCTURE
FLUORIDES
FLUORINE COMPOUNDS
FLUOROBORATES
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROLYSIS
IONIC CRYSTALS
IONS
LEAST SQUARE FIT
LYSIS
MAXIMUM-LIKELIHOOD FIT
MELTING
MONOCLINIC LATTICES
MONOCRYSTALS
NUMERICAL SOLUTION
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
SCATTERING
SIMULATION
SOLVOLYSIS
VALENCE
WATER
X-RAY DIFFRACTION
ZONE MELTING