Combined isotopic, chromatographic, and spectral determination of carbon dioxide in pure inorganic gases (survey)

Journal Article · Tue Dec 01 04:00:00 EST 1987 · Ind. Lab. (Engl. Transl.); (United States)

OSTI ID:7171610

Nemets, V M; Solov'ev, A A; Funtov, V N

There are major problems in determining CO/sub 2/ in pure inorganic gases on account of difficulties in making and storing standard specimens with low impurity contents. A combined isotopic, chromatographic, and spectral method can be employed based on cryogenic adsorption, which in principle allows one to determine low values of minor components without using such specimens. The method is used in this paper to determine CO/sub 2/ in pure inorganic gases: He, Ne, Ar, N/sub 2/, and H/sub 2/. The method includes the following steps: gas sampling; adding a known amount of carbon dioxide enriched in /sup 18/O; physicochemical transformation of the resulting analytical mixture (AM); and spectroscopic derivation of the isotope ratio c/sub C/sup 16/O/sub 3///c/sub C/sup 18/O/sub 2// = c/sub 1//c/sub 2/, with calculation of the unknown content c/sub x/ in mole %.

• Research Organization: Zhdanov Univ., Leningrad (USSR)
• OSTI ID: 7171610
• Journal Information: Ind. Lab. (Engl. Transl.); (United States), Journal Name: Ind. Lab. (Engl. Transl.); (United States) Vol. 53:6; ISSN INDLA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400101* -- Activation
Nuclear Reaction
Radiometric & Radiochemical Procedures
400102 -- Chemical & Spectral Procedures
400105 -- Separation Procedures
ADSORPTION
ARGON
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
CRYOGENICS
ELEMENTS
EVEN-EVEN NUCLEI
FLUIDS
GAS ANALYSIS
GAS CHROMATOGRAPHY
GASES
HELIUM
HYDROGEN
ISOTOPE RATIO
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
NEON
NITROGEN
NONMETALS
NUCLEI
OXIDES
OXYGEN 16
OXYGEN 18
OXYGEN COMPOUNDS
OXYGEN ISOTOPES
QUANTITATIVE CHEMICAL ANALYSIS
RADIOCHEMICAL ANALYSIS
RARE GASES
SENSITIVITY
SEPARATION PROCESSES
SORPTION
SPECTROSCOPY
STABLE ISOTOPES