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Contribution of fine particle sulfates to light scattering in St. Louis summer aerosol

Journal Article · · Environ. Sci. Technol.; (United States)
DOI:https://doi.org/10.1021/es00154a007· OSTI ID:7167146
The contribution of fine particle (NH/sub 4/)/sub 2/SO/sub 4/ to total light scattering was calculated from measured sulfur size distributions and estimates of water that might be associated with this deliquescent species. The most common type of sulfur size distribution observed had a major sulfur mass peak between 0.5 and 1.0 ..mu..m in diameter and was associated with the highest levels of b/sub scat/. A less common type with no peak above 0.5 ..mu..m was associated only with low values of b/sub scat/. On average, (NH/sub 4/)SO/sub 4/ plus associated water contributed 68% of the total light scattering due to particles during the summer of 1984. The measured light scattering coefficient, b/sub scat/, and (NH/sub 4/)/sub 2/SO/sub 4/ plus associated water were extremely well correlated. b/sub scat/ and total fine particle mass were not as well correlated, because the correlation between b/sub scat/ and non-sulfate fine mass was poor. The average calculated light scattering efficiency of (NH/sub 4/)/sub 2/SO/sub 4/ plus water was 4.2 m/sup 2//g. The higher values were associated with sulfur size distributions with a major peak above 0.5 ..mu..m.
Research Organization:
Washington Univ., St. Louis, MO
OSTI ID:
7167146
Journal Information:
Environ. Sci. Technol.; (United States), Journal Name: Environ. Sci. Technol.; (United States) Vol. 20:12; ISSN ESTHA
Country of Publication:
United States
Language:
English