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Title: Drift mobilities in amorphous silicon

Miscellaneous ·
OSTI ID:7156806

The author studied the nonlinear effects of the electric field on the drift mobilities of both electrons and holes in a series of undoped hydrogenated amorphous silicon (a-Si:H) and silicon-germanium alloy specimens. The author measured the transient photocurrents in pin diode structures as a function of electric field and temperature. Time-of-flight and charge collection measurements were conducted from which we concluded that the quantum efficiency for photo-carrier generation varied less than 10% for all specimens in this temperature and electric field range. In all cases transport was dispersive, but no evidence for field-dependence of the dispersion itself was found. The characteristic electric field for the onset of nonlinear electron transport increased with Ge concentration. In a-Si:H the author found a slight evidence for nonlinear transport of holes. The author presents a photocharge transient technique which allowed probing of the drift of electrons in several undoped a-Si:H specimens. The author found a unique feature of the transient photocharge associated with the thermal emission of the trapped electrons, strongly indicating that recombination occurs well after deep-trapping. The temperature dependence of the emission time revealed the mean energy of the trap distribution and the attempt-to-escape frequency associated with this trap. The author analyzed transient photocurrent and time-of-flight measurements in undoped a-Si:H for photocarrier motion both parallel and perpendicular to the thin-film growth axis. The author found a good agreement of the electron drift-mobility measurements and the electron mobility-lifetime product estimates for the two field directions for fifteen specimens. The data exclude an electron transport anisotropy in a-Si:H greater than a factor of two.

Research Organization:
Syracuse Univ., NY (United States)
OSTI ID:
7156806
Resource Relation:
Other Information: Thesis (Ph.D.)
Country of Publication:
United States
Language:
English