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Role of minerals in thermal alteration of organic matter. II. A material balance

Journal Article · · Am. Assoc. Pet. Geol., Bull.; (United States)
OSTI ID:7152875
Pyrolysis experiments were performed on Green River and Monterey Formation kerogens (Types I and II, respectively) with and without calcite, illite, or montmorillonite at 300/sup 0/C for 2 to 1000 hours under dry and hydrous conditions. Pyrolysis products were identified and quantified, and a material balance of product and reactants resulted. Applying the results to maturation of organic matter in natural environments, they suggest that a given type of organic matter associated with different minerals in source rocks will yield different products. Furthermore, the different adsorption capacities of minerals exert a significant influence on the migration of polar and high molecular weight compounds generated from the breakdown of kerogen. Therefore, the overall accumulated products from carbonate source rocks are mainly heavy oils with some gas, whereas light oils and gases are the main products from source rocks that contain expandable clays with catalytic and adsorptive properties. 8 figures, 2 tables.
Research Organization:
Univ. of California, Los Angeles
OSTI ID:
7152875
Journal Information:
Am. Assoc. Pet. Geol., Bull.; (United States), Journal Name: Am. Assoc. Pet. Geol., Bull.; (United States) Vol. 70:9; ISSN AAPGB
Country of Publication:
United States
Language:
English