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U.S. Department of Energy
Office of Scientific and Technical Information

Drilling fluids based on sulfonated elastomeric polymers

Patent ·
OSTI ID:7151853
The present invention relates to sulfonated elastomeric polymers which are copolymers of isoprene and sodium styrene sulfonate or teropolymers of isoprene, styrene and sodium styrene sulfonate wherein these sulfonated polymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated and elastomeric polymers have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated elastomeric polymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated elastomeric polymer, wherein the polar cosolvent increases the solubility of the sulfonated elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.
Assignee:
Exxon Research and Engineering Co.
Patent Number(s):
US 4425462
OSTI ID:
7151853
Country of Publication:
United States
Language:
English