Synthesis and characterization of sodium-titanium phosphates, Na/sub 4/(TiO)(PO/sub 4/)/sub 2/, Na(TiO)PO/sub 4/, and NaTi/sub 2/(PO/sub 4/)/sub 3/*

Journal Article · Thu Mar 31 23:00:00 EST 1988 · J. Solid State Chem.; (United States)

DOI:https://doi.org/10.1016/0022-4596(88)90115-6· OSTI ID:7148561

Bamberger, C E; Begun, G E; Cavin, O B

Experimental examination of part of the system Na/sub 2/O-TiO/sub 2/-P/sub 2/O/sub 5/ revealed the existence of two new sodium-titanium phosphates, Na(TiO)(PO)/sub 4/ and Na(TiO)P)/sub 4/. Their synthesis was accomplished by several different reactions and their identity was established by means of Raman spectroscopy and X-ray diffraction. Additionally, novel reactions for the synthesis of NaTi/sub 2/(PO/sub 4/)/sub 3/ have been demonstrated.

• Research Organization: Oak Ridge National Lab., TN (USA)
• DOE Contract Number: AC05-84OR21400
• OSTI ID: 7148561
• Journal Information: J. Solid State Chem.; (United States), Journal Name: J. Solid State Chem.; (United States) Vol. 73:2; ISSN JSSCB
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
CHEMICAL PREPARATION
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
HIGH TEMPERATURE
INFORMATION
MOLTEN SALTS
NUMERICAL DATA
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
RAMAN SPECTRA
SALTS
SCATTERING
SODIUM COMPOUNDS
SPECTRA
SYNTHESIS
TITANATES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION