Piezochromism: Pressure-induced isomerizations in the tetrachlorocuprate anion in the solid state with various cations
Journal Article
·
· Journal of Physical Chemistry; (USA)
- Univ. of Illinois, Urbana-Champaign (USA)
The effects of high pressure on Cs{sub 2}CuCl{sub 4}, bis(trimethylbenzylammonium) tetrachlorocuprate, (N-phenylpiperazinium) tetrachlorocuprate, bis(N-benzylpiperazinium) tetrachlorocuprate bis(hydrochloride), and bis(N-methylphenethylammonium) tetrachlorocuprate are reported. Electronic spectroscopy indicates molecular rearrangements in the tetrachlorocuprate ions with increasing pressure. The changes in geometry and nature of the rearrangements are discussed.
- DOE Contract Number:
- AC02-76ER01198
- OSTI ID:
- 7145083
- Journal Information:
- Journal of Physical Chemistry; (USA), Vol. 94:5; ISSN 0022-3654
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CESIUM CHLORIDES
ELECTRONIC STRUCTURE
CUPRATES
DATA ANALYSIS
EXPERIMENTAL DATA
HIGH PRESSURE
MEASURING INSTRUMENTS
MEASURING METHODS
PRESSURE DEPENDENCE
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
COPPER COMPOUNDS
DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
360104* - Metals & Alloys- Physical Properties
400201 - Chemical & Physicochemical Properties
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CESIUM CHLORIDES
ELECTRONIC STRUCTURE
CUPRATES
DATA ANALYSIS
EXPERIMENTAL DATA
HIGH PRESSURE
MEASURING INSTRUMENTS
MEASURING METHODS
PRESSURE DEPENDENCE
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
COPPER COMPOUNDS
DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
360104* - Metals & Alloys- Physical Properties
400201 - Chemical & Physicochemical Properties