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Thermodynamics of mixing C/sub 6/ and C/sub 7/ compounds with a bicyclic compound at infinite dilution

Journal Article · · J. Solution Chem.; (United States)
DOI:https://doi.org/10.1007/BF00652584· OSTI ID:7143778
The activity coefficients at infinite dilution have been measure at 25/sup 0/C for cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene, benzene, n-hexane, 1-hexene, 1-hexyne, n-heptane, 1-heptene and 1-heptyne in decahydronaphthalene, bicyclohexyl, 1,2,3,4-tetrahydronaphthalene and cyclohexylbenzene. These results, together with previously determined H/sup E//sub m/ and V/sup E//sub m/ have been used to calculate the partial molar excess thermodynamic properties of mixing at infinite dilution.
Research Organization:
Rhodes Univ., Grahamstown (South Africa)
OSTI ID:
7143778
Journal Information:
J. Solution Chem.; (United States), Journal Name: J. Solution Chem.; (United States) Vol. 16:12; ISSN JSLCA
Country of Publication:
United States
Language:
English